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Direct conversion of methane, other hydrocarbons, and alcohol at lower temperatures can be achieved using plasma or an electric field and catalysts. Non-equilibrium plasma enables activation of stable molecules including methane, carbon dioxide, and water, even at low temperatures, by virtue of high electron energy. Use of a hybrid system of plasma and catalyst provided high conversion and selectivity to products by virtue of adsorption on the catalyst. Imposing a DC electric field to the catalyst bed also promotes catalytic reactions, even at low temperatures. Two mechanisms for electro-catalytic reactions are proposed for the DC electric field imposition: reactant activation by surface protonics and production of active surface oxygen species on the catalyst. This review presents summaries of these novel processes.
Chem Rec 2017 Aug
PMID:Catalytic Reaction Assisted by Plasma or Electric Field. 2814 43

Supported bimetallic catalysts have been studied because of their enhanced catalytic properties due to metal-metal interactions compared with monometallic catalysts. We focused on galvanic deposition (GD) as a bimetallization method, which achieves well-defined metal-metal interfaces by exchanging heterogeneous metals with different ionisation tendencies. We have developed Ni@Ag/SiO2 catalysts for CO oxidation, Co@Ru/Al2 O3 catalysts for automotive three-way reactions and Pd-Co/Al2 O3 catalysts for methane combustion by using the GD method. In all cases, the catalysts prepared by the GD method showed higher catalytic activity than the corresponding monometallic and bimetallic catalysts prepared by the conventional co-impregnation method. The GD method provides contact between noble and base metals to improve the electronic state, surface structure and reducibility of noble metals.
Chem Rec 2018 Sep
PMID:Synthesis of Supported Bimetal Catalysts using Galvanic Deposition Method. 2946 73

ffinlo Costain argues that the focus on ruminant methane in causing global warming is ill-informed and in fact restoration of grass-based systems can result in net zero emissions from UK agriculture by 2030.
Vet Rec 2019 10 12
PMID:'Livestock are not the global warming enemy'. 3195 94

Pete Smith and Andrew Balmford argue that methane from livestock is an important contributor to climate change and that it should not be creatively discounted.
Vet Rec 2020 01 18
PMID:Climate change: 'no get out of jail free card'. 3205 10


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