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Target Concepts:
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Query: UNIPROT:Q86TM3 (
cage
)
29,987
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
For the first time, Th@
T
d
(19151)
-
C
76
, a highly symmetric C
76
cage
encapsulating an actinide metal ion, has been synthesized and characterized by single-crystal X-ray crystallography, mass spectrometry, UV-vis-NIR spectroscopy, and cyclic voltammetry. The single-crystal crystallographic analysis unambiguously assigned the fullerene
cage
as
T
d
(19151)-C
76
and confirmed Th@
T
d
(19151)-C
76
as the first
IPR
(isolated-pentagon rule) C
76
-based monometallofullerene. The crystallographic results further revealed that the optimal Th site resides over a sumanene-type hexagon, similar to that of the Th@
C
1
(11)-C
86
but different from the previously reported Th@
C
3
v
(8)-C
82
. In addition, electrochemical study found that Th@
T
d
(19151)
-
C
76
processes an unusually low first oxidation potential (0.03 V), suggesting its strong electron donating ability.
...
PMID:Th@
T
d
(19151)
-
C
76
: A Highly Symmetric Fullerene Cage Stabilized by a Tetravalent Actinide Metal Ion. 3177 50
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