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Query: UNIPROT:Q86TM3 (
cage
)
29,987
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
Thermodynamic stability boundary in the structure-H methane +
bromocyclopentane
mixed hydrate system was measured at pressures from 20 to 100 MPa. The thermodynamic stability boundary of the methane +
bromocyclopentane
mixed hydrate exhibits anomalous behavior under conditions at high pressures and high temperatures. This phenomenon is due to the elimination and substitution reactions of
bromocyclopentane
to cyclopentene and cyclopentanol, respectively. The nucleophilic reactions of
bromocyclopentane
are mainly advanced in the liquid
bromocyclopentane
-rich phases, while it is restrained when
bromocyclopentane
is enclathrated in hydrate
cage
.
...
PMID:Nucleophilic reactions of bromocyclopentane in the structure-H methane + bromocyclopentane mixed hydrate system at high pressures. 2501 39
