Gene/Protein Disease Symptom Drug Enzyme Compound
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Query: UNIPROT:P50583 (asymmetrical)
 12,197 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

Spinach chloroplasts are spread at a heptane-water interface. Applying a novel capacitative electrode introduced in the preceding paper (Trissl, H.-W. (1980) Biochim. Biophys. Acta 595, 82-95) the changes of the interface potential induced by single laser flashes are investigated. The following results are obtained: (1) The chloroplasts spread at the interface form a thin layer with asymmetrical orientation. The structural state of this layer is discussed. (2) The photovoltage from the interfacial layer shows similar characteristics as the field-indicating absorption change of chloroplast suspensions, the latter reflecting the photosynthetic primary charge separation: (a) Both can be abolished by addition of 3-(3',4'-dichlorophenyl)-1,1-dimethylurea. (b) About one half of the signals can be reactivated by addition of N-methyl-phenazonium methosulfate. (c) Both signals saturate at low flash light intensities. (d) Both signals can be abolished by background illumination of comparable intensities. (e) Both signals are independent of the ionic strength. (3) The half-rise time of the photovoltage is determined to be less than 3 ns. It is suggested from these results that the photovoltage from the interfacial layer reflects the primary charge separation process in photosynthesis, i.e. the latter is accomplished also within less than 3 ns.
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PMID:II. Electrical measurements in the nanosecond range of the charge separation from chloroplasts spread at a heptane-water interface. Application of a novel capacitive electrode. 734 87

The synthetic and functional versatility of dendrimers and their well-defined shapes make them attractive molecules for surface modification. We synthesized six structurally very similar surface-bound dendrons and used them as building blocks for the preparation of self-assembled monolayers (SAMs) on a gold surface. We studied the effects of the surface-bound dendron's main structure, peripheral substituents, and the coadsorption process on its self-assembling behavior. Using scanning tunneling microscopy (STM), we observed nanostripes for SAMs of the surface-bound dendron consisting of symmetrical benzene rings. When we changed the symmetrical dendron's structure slightly, by increasing or decreasing the numbers of benzene rings at one wedge, we found no ordered structures were formed by the asymmetrical dendrons. We also introduced two kinds of substituents, heptane chains and oligo(ethylene oxide) chains, to the symmetrical dendron's periphery. Heptane chains appear to enhance the interaction between symmetrical backbones, leading to the formation of stripes, while oligo(ethylene oxide) chains appear to weaken the interaction between symmetrical backbones, resulting in a homogeneous structure. Dendrons with both heptane and oligo(ethylene oxide) chains exhibit nanophase separation in a confined state, leading to the formation of a honeycomb structure. Electrochemical studies provide additional evidence for understanding the resulting surface organizations: surface-bound dendrons with symmetrical structures form denser monolayers than their asymmetrical analogues; SAMs comprising peripherally substituted dendrons exhibit blocking effects proportionate to their hydrophilic fraction.
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PMID:Self-assembled monolayers of novel surface-bound dendrons: peripheral structure determines surface organization. 1277 8

We have reported the study of methanol/AOT/n-heptane reverse micellar aggregates using Fourier Transform Infrared (FTIR) spectroscopy. We have divided our whole work into two parts. In the first part we have studied the structural properties of Aerosol OT (AOT) reverse micelles by monitoring the changes in the symmetrical sulfonate stretching region (1000-1100 cm(-1)), asymmetrical sulfonate stretching region (1130-1330 cm(-1)) and carbonyl frequency region (1695-1770 cm(-1)), and in the other part we have measured the changes in the maximum position of OH stretching frequency region (3140-3650 cm(-1)) with increasing methanol content of the reverse micellar solution. Finally we have defined and established the presence of different types of methanol inside the reverse micelle by splitting the OH frequency region using multiple Gaussian curve fitting. Though methanol is partially soluble in n-heptane, this work certainly proves the existence of stable methanol/AOT/n-heptane reverse micelles.
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PMID:To probe the structure of methanol and Aerosol OT (AOT) in AOT reverse micelles by FTIR measurements. 2044 37