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Query: UNIPROT:P39060 (
endostatin
)
2,284
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
Finding new organic materials to address several issues (e.g. capacity, stability, and cycle life) in organic potassium-ion batteries (OPIBs) is very important and highly desirable. Here, to directly investigate the redox reaction of organic pyridine dicarboxylate in OPIBs and to avoid the interference from the redox-active metal ions, a non-redox-metal potassium metal-organic framework (K-
MOF
), [C
7
H
3
KNO
4
]
n
, based on pyridine-2,6-dicarboxylic acid (H
2
PDA), has been successfully synthesized and applied as a promising organic anode for long-cycle life PIBs. The crystal structure of [C
7
H
3
KNO
4
]
n
was confirmed by single-crystal X-ray diffraction analysis and FT-IR spectra. Moreover, the potassium-storage mechanism of organic pyridine dicarboxylate ligand was revealed by ex situ FT-IR/XRD characterization and theoretical calculations. The as-synthesized K-
MOF
resulted in a unique and reversible three-step redox reaction, exhibited superior electrochemical performance with the aid of N-K/O-K coordination bonds, and showed a high average specific capacity of 115 mA h g
-1
at 100 mA g
-1
for 300 cycles with the capacity retention of 92%.
...
PMID:Nanostructured potassium-organic framework as an effective anode for potassium-ion batteries with a long cycle life. 3222 17
