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Query: UMLS:C1835664 (TOC)
 2,763 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

The organic fraction of a sludge from a wastewater biological treatment plant is characterized by the total organic carbon, TOC, content, cyclohexane and toluene extractions, and thermal desorptions in nitrogen and air flow at different temperatures. The inorganic fraction is characterized by water extraction, FT-IR spectroscopy, thermogravimetric analysis, and scanning electron microscopy/energy dispersion X-ray analysis. The thermal degradation rate of organic carbon is studied in batch experiments in air, in the 250-500 degrees C temperature range. The sample TOC is used to measure the decrease of reagent concentration with time. The TOC vs time data are well fitted by a generalized kinetic model, previously proposed for the MSWIs fly ash thermal degradation. The rate constants of the immediate carbon gasification, k2, and of the dissociative oxygen chemisorption, k1, followed by C(O) intermediate gasification, k3, together with activation and thermodynamic parameters are calculated. The rate determining step is the C(O) oxidation. The influence of desorbed or extracted organic compounds on kinetics and the role of the C(O) formation in explaining the reaction mechanism as well as the comparison with fly ash kinetics are discussed.
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PMID:Thermal oxidation kinetics and mechanism of sludge from a wastewater treatment plant. 1164 66

Nutrients and other pollutant runoffs from streams in artificial forest areas in central Hyogo Prefecture in southwest Japan have been investigated to estimate pollutant loads since 1995. The orthophosphate and ammonium nitrogen contents were usually low and constant during the investigation. When the flowrates of the streams were normal, the concentrations of suspended solids, COD(Mn), TOC and total phosphorus were very low, and did not change much. However, when stream flows were increased by rainstorms or other precipitation, higher concentrations of these parameters occurred. Otherwise, the average concentrations of nitrate nitrogen and total nitrogen were 0.26 mg/l and 0.31 mg/l, respectively, and they were often increased by precipitation events. They changed at the same time because the ratio of nitrate nitrogen per total nitrogen was high, about 80%. The fluctuation of concentrations of total phosphorus was similar to SS concentrations, which suggested that phosphorus was discharged in the types of suspended solids from forest areas. The specific loads of the nutrients and some other pollutants did not differ among the three watersheds investigated. However, the difference among them between fine days and rainy days was fairly large. It was presumed that pollutant runoff from forest areas is strongly dependent on precipitation events.
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PMID:Runoff characteristics of nutrients in the forest streams in Hyogo Prefecture, Japan. 1172 81

The mixture of five yeast strains obtained from soil could remove about 85% TOC of oil-rich wastewater in batch test. While the highest MLSS was obtained at an N:C of 1:5, the oil removal decreased with the increase of N:C during yeast sludge cultivation. Ammonium chloride was the best nitrogen source for yeast cultivation from the viewpoint of yeast growth and oil utilization. An ammonia concentration of over 1300 mg/L led to mass death of yeast at a pH of 5. The ammonia concentration should be controlled at a level of 1000 mg/L or lower.
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PMID:Seed yeast cultivation for salad oil manufacturing wastewater treatment. 1188 16

This paper examines the correlations between some water quality parameters and fluorescence intensities and spectra in filtered wastewater using a 280 nm excitation wavelength. We did not obtain satisfying linear relationships between fluorescence and COD or TOC (r2 approximately 0.4) for any of the emission wavelengths used between 320 and 400 nm (especially at 355 nm, the average emission lambda(max.)). The relationships with NK were better (r2 approximately 0.7); leading us to suggest that one evaluates mainly the organic nitrogen content at lambda(ex.) = 280 nm. Whole spectra processing did not improve the correlations. Gel permeation chromatography yielded markedly different TOC and fluorescence chromatograms, which explains the difficulty of correlating organic content and fluorescence. Other investigations are necessary before spectrofluorimetry can be used as a reliable technique for on-line wastewater pollution estimation.
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PMID:On the use of fluorescence measurements to characterize wastewater. 1193 23

Landfill leachate characterization is a critical factor in establishing a corresponding effective management strategy or treatment process. However, it is often difficult to forecast leachate quality because of a variety of influencing factors such as waste composition and landfill operations. This paper describes leachate formation mechanisms, summarizes leachate quality indicators, and investigates the temporal variation of leachate quality from pre-sorted and baled municipal solid waste characterized with high organic and moisture content. The purpose of the study is to evaluate the potential effects of waste composition and site-specific operational procedures on biodegradation processes and leachate quality at a field-scale landfill that receives in excess of 1800 tonnes per day of refuse. For this purpose, waste disposal and leachate generation rates were monitored and leachate samples were collected for a period of 18 months during the early stages of refuse deposition. Chemical analysis was performed on the samples and the temporal variation of several parameters were monitored including pH, COD, TOC, TDS, chlorides, sulfates, orthophosphates, nitrates, ammonia nitrogen, hardness, and heavy metals. Chemical concentration levels were related to biological activity within the landfill and the results indicated that: (1) pre-sorting and baling of the waste did not hinder waste stabilization; and (2) the high organic and moisture contents resulted in an extremely strong leachate, particularly at the onset of biodegradation processes, which can affect the leachate treatment facility.
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PMID:Temporal variation of leachate quality from pre-sorted and baled municipal solid waste with high organic and moisture content. 1195 74

Simultaneous biological phosphorus and nitrogen removal with enhanced anoxic phosphate uptake was investigated in an anaerobic-aerobic-anoxic-aerobic sequencing batch reactor ((AO)2 SBR). Significant amounts of phosphorus-accumulation organisms (PAOs) capable of denitrification could be accumulated in a single sludge system coexisting with nitrifiers. The ratio of the anoxic phosphate uptake to the aerobic phosphate uptake capacity was increased from 11% to 64% by introducing an anoxic phase in an anaerobic aerobic SBR. The (AO)2 SBR system showed stable phosphorus and nitrogen removal performance. Average removal efficiencies of TOC, total nitrogen, and phosphorus were 92%, 88%, and 100%, respectively. It was found that nitrite (up to 10 mg NO2(-)-N/l) was not detrimental to the anoxic phosphate uptake and could serve as an electron acceptor like nitrate. In fact, the phosphate uptake rate was even faster in the presence of nitrite as an electron acceptor compared to the presence of nitrate. It was found that on-line sensor values of pH, ORP, and DO were somehow related with the dynamic behaviours of nutrient concentrations (NH4+, NO3-, and PO4(3-)) in the SBR. These on-line sensor values were used as real-time control parameters to adjust the duration of each operational phase in the (AO)2 SBR. The real-time controlled SBR exhibited better performance in the removal of phosphorus and nitrogen than the SBR with fixed-time operation.
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PMID:Biological nitrogen removal with enhanced phosphate uptake in a sequencing batch reactor using single sludge system. 1223 Jan 80

The performance of the submerged membrane separation activated sludge process with intermittent aeration was investigated in a laboratory scale experiment by changing organic loading rate and intermittent aeration cycle. A rectangular PVC tank was used as an aeration tank, in which a flat-sheet type Micro-Filtration membrane made of poly-olefin with a pore size of 0.2 microm was submerged. Organic loading rate to the reactor was set at 0.3 and 0.8 g-TOC/L/day. C/N ratio in the feed was set at around 5.0 for every condition. Aeration cycle was changed from 10 min-10 min (aeration-stop) to 120 min-120 min in different organic loading conditions. Flux through the membrane was set at 0.25 m/day. Membrane fouling proceeded rapidly in 0.8 g-TOC/L/day conditions. However, when organic loading rate was 0.3 g-TOC/L/day, bacterial metabolic substances were degraded rapidly compared to the production, thereby decreasing viscosity in mixed liquor. Nitrogen removal rate was between 60% and 80% for 0.8 g-TOC/L/day loading, and between 50% and 65% for 0.3 g-TOC/L/day loading. And the nitrogen removal was highest in 40 min to 60 min aeration cycle conditions. Too short aeration cycle did not result in sufficiently long anoxic periods for denitrification while too long a cycle resulted in unnecessary anaerobic periods after depletion of nitrate. Intermittent aeration was effective also for decreasing viscosity in mixed liquor.
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PMID:Effect of loading rate and intermittent aeration cycle on nitrogen removal in membrane separation activated sludge process. 1242 Sep 74

This study was undertaken to examine the degradation of TNT, RDX and HMX in a circular photocatalytic reactor with TiO2 as a photocatalyst. We examined the impact of parameters such as the initial concentration, initial pH of solution on rates of photocatalized transformation, and the mineralization. The results showed that photocatalysis is an effective process for the degradation of TNT, RDX and HMX. They could be comoletely degraded in 150 min with 1.0 g/L TiO2 at pH 7. An increase in the photocatalytic degradation of HMX was noticed with decreasing initial HMX. The rates of RDX and HMX degradation were greater in neutral pH than in acidic and alkaline conditions. In case of TNT degradation, the rate of degradation was the fastest at pH 11. Approximately 82% TOC decrease in the TNT degradation was achieved after 150 min, whereas TOC decrease in RDX and HMX was 24% and 59%, respectively. Nitrate, nitrite, and ammonium ions were detected as the nitrogen byproducts from the photocatalysis, and more than 50% of the total nitrogen was recovered as nitrate ion in every explosives.
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PMID:Photocatalytic degradation of explosives contaminated water. 1252 45

The standard method for determining the 15N abundance of total dissolved nitrogen (TDN) in aqueous samples (e.g., soil leachate, sewage, urine) is currently Kjeldahl digestion followed by steam distillation or diffusion to isolate the ammonium, and then 15N measurement using IRMS. However, this technique is both time-consuming and laborious. One way of overcoming these disadvantages could be to couple a TOC analyser to determine the TDN with a sufficient quadrupole MS to determine the 15N abundance. The high TOC analyser (Elementar Analysensysteme Hanau, Germany), which catalytically oxidises the sample's total nitrogen with a high, constant yield to nitrogen monoxide (NO), appeared particularly suitable. The quadrupole-MS ESD 100 (InProcess Instruments Bremen, Germany) proved to be a suitable mass spectrometer for the 15N determination of NO. This combination of instruments was found to provide a workable method in numerous measurements of standard and actual samples. The detection limit concerning the N amount required per analysis is 2 microg, corresponding to an N concentration of 0.7 mg/l in a maximum sample volume of 3ml. Depending on the N concentration, 15N abundances starting from 0.5 at.% can be measured with the required precision of better than 3% (simple standard deviation). For example, measuring the abundance of 0.5 at.% requires about 50 microg N, whereas for 1 at.% or more only about 5 microg N is needed per analysis.
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PMID:A new approach to determining the content and 15N abundance of total dissolved nitrogen in aqueous samples: TOC analyser-QMS coupling. 1272 25

The responses of a steady-state, continuous-flow, completely-mixed fluidized bed reactor (FBR) to a range of monoethylamine (MEA) impulses are analyzed in terms of its combined carbon oxidation and nitrification efficiencies. Immobilized cells are cultivated at a mean cell residence time (MCRT) that exceeds 75 days. Responses due to bacterial activities and physical flows are separately estimated using a methodology based on mass balance calculations. MEA inhibition becomes evident when respective critical impulse loadings are exceeded, i.e., 0.12 mg TOC/mg VS for carbon oxidation and 0.021 mg TOC/mg VS for nitrification (TOC: total organic carbon, VS: volatile solids). Nitrifying cells are shown to be more susceptible to MEA impulses than their heterotrophic counterparts. However, the presence of nitrification activities under the conditions tested demonstrates the advantages of cell immobilization that offer greater flexibility when challenged with suddenly increased MEA loads over a short period of time. Mass balance calculations on nitrogen species confirms that 0.583 mg NH(4)(+)-N is produced per mg MEA-C removed when the assimilatory nitrogen requirements for cell synthesis are negligible.
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PMID:Impulse responses of a monoethylamine-fed fluidized bed reactor. 1272 42


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