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Nitrogen and phosphorus removal in a methane fermentation plus activated sludge method type pig farm (M-III) with an intermittent aeration process (IAP) was evaluated in comparison with a continuous aeration process (CAP) based on the full-scale and bench-scale experiments. Operation conditions for the treatment system were the same except for the aeration program (in the CAP), a consecutive 24-hr aeration was used, whereas in the IAP, the aeration and non-aeration periods were alternated at intervals of 3:1 hr. BOD and TOC removal efficiencies with the intermittent aeration were as high as those with the continuous operation (92-98%). In the removal of nitrogen and phosphorus, large differences between IAP and CAP were observed. At an influent T-N/TOC ratio of 0.1, removal efficiencies for T-N in the bench-scale IAP was 70%, and for T-P was 22%, respectively. At an even higher influent T-N/TOC ratios of 0.3-1.0, the removal efficiencies for T-N were decreased to about 59-61%, whereas that for T-P were -0.3-13%. In a full-scale plant, removal efficiencies for T-N with IAP and CAP were 42% and -0.09%, respectively. The results of this study show the successful performance of a simple IAP for piggery wastewater: simultaneous, one-sludge denitrification with nitrification in single-activated sludge reactor in a pig farm.
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PMID:Removal of nitrogen and phosphorus from swine wastewater by intermittent aeration processes. 851 70

A process on crystallized precipitation of ammonium by adding magnesium salt and phosphate was carried out to improve C/N ratio in swine wastewater. After completion of crystallized precipitation of ammonium, an intermittent aeration process with aeration and nonaeration periods alternated at interval of 1:1 hr day-1 is used for the improved swine wastewater (T-N/BOD = 0.14: BOD = 8200 mg/liter and T-N = 1166 mg/liter). The results obtained from the experiment show that the removal ratios of T-N and NH4-N are 91% and 99%, respectively. T-P is not removed, while the removal ratio of PO4-P is 60% as 3% of CaCl2 liquid is added. The results also indicate that dilution with water is effective to improve the removal of phosphorus even if raw swine wastewater contains high concentrations of T-N, T-P, BOD, and TOC.
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PMID:Nitrogen and phosphorus removal for swine wastewater by ammonium crystallization and intermittent aeration process. 852 33

Nutrients and other pollutant runoffs from streams in artificial forest areas in central Hyogo Prefecture in southwest Japan have been investigated to estimate pollutant loads since 1995. The orthophosphate and ammonium nitrogen contents were usually low and constant during the investigation. When the flowrates of the streams were normal, the concentrations of suspended solids, COD(Mn), TOC and total phosphorus were very low, and did not change much. However, when stream flows were increased by rainstorms or other precipitation, higher concentrations of these parameters occurred. Otherwise, the average concentrations of nitrate nitrogen and total nitrogen were 0.26 mg/l and 0.31 mg/l, respectively, and they were often increased by precipitation events. They changed at the same time because the ratio of nitrate nitrogen per total nitrogen was high, about 80%. The fluctuation of concentrations of total phosphorus was similar to SS concentrations, which suggested that phosphorus was discharged in the types of suspended solids from forest areas. The specific loads of the nutrients and some other pollutants did not differ among the three watersheds investigated. However, the difference among them between fine days and rainy days was fairly large. It was presumed that pollutant runoff from forest areas is strongly dependent on precipitation events.
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PMID:Runoff characteristics of nutrients in the forest streams in Hyogo Prefecture, Japan. 1172 81

Bioreactor retention time is a key process variable that will influence costs that are relevant to long distance space travel or long duration space habitation. However. little is known about the effects of this parameter on the microbiological treatment options that are being proposed for Advanced Life Support (ALS) systems. Two bioreactor studies were designed to examine this variable. In the first one, six retention times ranging from 1.3 to 21.3 days--were run in duplicate, 81 working-volume continuous stirred tank reactors (CSTR) that were fed ALS wheat residues. Ash-free dry weight loss, carbon mineralization, soluble TOC reduction, changes in fiber content (cellulose, hemicellulose, and lignin), bacterial numbers, and mineral recoveries were monitored. At short retention times--1.33 days--biodegradation was poor (total: 16-20%, cellulose - 12%, hemicellulose - 28%) but soluble TOC was decreased by 75-80% and recovery of major crop inorganic nutrients was adequate, except for phosphorus. A high proportion of the total bacteria (ca. 83%) was actively respiring. At the longest retention time tested, 21.3 days, biodegradation was good (total: 55-60%, cellulose ca. 70%, hemicellulose - ca. 55%) and soluble TOC was decreased by 80%. Recovery of major nutrients, except phosphorus, remained adequate. A very low proportion of total bacteria was actively respiring (ca. 16%). The second bioreactor study used potato residue to determine if even shorter retention times could be used (range 0.25-2.0 days). Although overall biodegradation deteriorated, the degradation of soluble TOC continued to be ca. 75%. We conclude that if the goal of ALS bioprocessing is maximal degradation of crop residues, including cellulose, then retention times of 10 days or longer will be needed. If the goal is to provide inorganic nutrients with the smallest volume/weight bioreactor possible, then a retention time of 1 day (or less) is sufficient.
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PMID:Recovery of resources for advanced life support space applications: effect of retention time on biodegradation of two crop residues in a fed-batch, continuous stirred tank reactor. 1213 28

Simultaneous biological phosphorus and nitrogen removal with enhanced anoxic phosphate uptake was investigated in an anaerobic-aerobic-anoxic-aerobic sequencing batch reactor ((AO)2 SBR). Significant amounts of phosphorus-accumulation organisms (PAOs) capable of denitrification could be accumulated in a single sludge system coexisting with nitrifiers. The ratio of the anoxic phosphate uptake to the aerobic phosphate uptake capacity was increased from 11% to 64% by introducing an anoxic phase in an anaerobic aerobic SBR. The (AO)2 SBR system showed stable phosphorus and nitrogen removal performance. Average removal efficiencies of TOC, total nitrogen, and phosphorus were 92%, 88%, and 100%, respectively. It was found that nitrite (up to 10 mg NO2(-)-N/l) was not detrimental to the anoxic phosphate uptake and could serve as an electron acceptor like nitrate. In fact, the phosphate uptake rate was even faster in the presence of nitrite as an electron acceptor compared to the presence of nitrate. It was found that on-line sensor values of pH, ORP, and DO were somehow related with the dynamic behaviours of nutrient concentrations (NH4+, NO3-, and PO4(3-)) in the SBR. These on-line sensor values were used as real-time control parameters to adjust the duration of each operational phase in the (AO)2 SBR. The real-time controlled SBR exhibited better performance in the removal of phosphorus and nitrogen than the SBR with fixed-time operation.
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PMID:Biological nitrogen removal with enhanced phosphate uptake in a sequencing batch reactor using single sludge system. 1223 Jan 80

The purpose of this study was to investigate the effect of phosphorus addition on biological pretreatment of raw water. Experiments were conducted in pilot-scale bio-ceramic filters with raw water from a reservoir located in Beijing, China. The results demonstrated that phosphorus was the limiting nutrient for bacterial growth in the raw water investigated in this study. The measured values of bacterial regrowth potential (BRP) and biodegradable dissolved organic carbon (BDOC) of the raw water increased by 50-65% and 30-40% with addition of 50 microg of PO4(3-)-PL(-1), respectively. Addition of 25 microg of PO4(3-)-PL(-1) to the influent of bio-ceramic filter enhanced the percent removal of organics by 4.6, 5.7 and 15 percentage points in terms of COD(Mn), TOC and BDOC, respectively. Biomass in terms of phospholipid content increased by 13-22% and oxygen uptake rate (OUR) increased by 35-45%. The ratio of C:P for bacteria growth was 100:1.6 for the raw water used in this study. Since change of phosphorus concentrations can influence the performance of biological pretreatment and the biological stability of drinking water, this study is of substantial significance for waterworks in China. The role of phosphorus in biological processes of drinking water should deserve more attention.
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PMID:Improvement of organics removal by bio-ceramic filtration of raw water with addition of phosphorus. 1456 58

Addition of phosphorus as a novel way to improve the performance of bio-ceramic filter for biological pretreatment of source water was conducted. More bacteria grown in raw water and the BDOC of raw water increased when 50 micrograms/L PO4(3-)-P (NaH2PO4) was added alone were clear evidence of phosphorus limitation on bacterial growth. It shown that about 4.7%, 3.6% and 5.7% more of COD(Mn), UV254 and TOC from the raw water investigated in the experiment on the average was removed respectively when 25 micrograms/L PO4(3-)-P (H3PO4) was added to the influent of bioceramic filter. The role of phosphorus in raw water and drinking water should be paid more attention.
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PMID:[Improvement of biological pretreatment performance by addition of phosphorus]. 1471 65

Removal efficiency of TOC ranged between 86-89% in an intermittently aerated reactor. High efficiency in TKN removal and nitrification was found at lower applied load or longer retention time such as 2 days. TKN removal and nitrification efficiency was found to be 17-96% and 35-99% respectively. Through examination and comparison of the removal efficiencies, the stability of nitrification/denitrification and the biological phosphorus removal it was found that the sequencing batch feeding system gave a higher performance in total nitrogen and phosphorus removals. In the SBR reactor, nitrogen removal efficiency was mainly controlled by organic loading. Nitrification efficiency ranged between 31-56%. Nearly complete denitrification was observed in the sequencing batch reactor.
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PMID:Comparison of intermittently aerated continuous and batch biofilm reactor in nutrient removal. 1475 58

This study compared the swine wastewater treatment of two identical lab-scale two-stage sequencing batch reactors (TSSBR) under similar conditions except that one was operated on a fixed-time mode and the other on a real-time mode. While both TSSBR systems performed very well, the real-time TSSBR performed far better then the fixed-time TSSBR, in every aspect of carbon, nitrogen, and phosphorous removal. The removals of COD, TOC, were at 97% and for BOD5 even at 99.7%. In terms of NH4-N and TKN removals, the real-time TSSBR achieved removal of over 98%. For phosphorus removals (Ortho-P and total P) the results from the real-time TSSBR was quite remarkable at 97.7%.
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PMID:A comparison of swine wastewater treatment using real-time and fixed-time two-stage sequencing batch reactors. 1518 36

Separately collected urine ("yellow water") can be utilized as fertilizer. In order to decrease storage volumes and energy consumption for yellow water transport to fields, enrichment of nutrients in yellow water has to be considered. Laboratory-scale batch freeze concentration of yellow water has been tested in ice-front freezing apparatus: a stirred vessel and a falling film freeze concentrator (coolant temperatures: -6 to -16 degrees C). With progressing enrichment of the liquid concentrate, the frozen ice was increasingly contaminated with yellow water constituents (ammonia, total nitrogen, total phosphorus, TOC, and salts determined as conductivity). The higher the initial salinity of the yellow water and the lower the mechanical agitation of the liquid phase contacting the growing ice front, the more the frozen ice was contaminated. The results indicate, that in ice-front freezing devices multistage processes are necessary, i.e. the melted ice phase has to be purified (and the concentrates must be further enriched) in a second or even in a third stage. Energy consumption of this process is very high. However, technical scale suspension freeze concentration is reasonable in centralized ecological sanitation schemes if the population exceeds 0.5 million and distance of yellow water transportation to fields is more than 80 km.
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PMID:Freeze concentration for enrichment of nutrients in yellow water from no-mix toilets. 1553 91


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