Gene/Protein Disease Symptom Drug Enzyme Compound
Pivot Concepts:   Target Concepts:
Query: UMLS:C0847097 (acidity)
 15,165 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

In the title compound, [Mo(C7H7NO2S)2Cl2(C4H10O2)], the Mo-Cl bond lengths are 2.3730 (8) and 2.3842 (8) A, the former being the shortest within the series of analogous structurally characterized bis(imido) Mo complexes. This fact clearly explains the very strong Lewis acidity of the metal centre in this complex and, as a result, its synthetic versatility as a nitrene transfer reagent towards different phosphanes and strained cycloolefins.
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PMID:Dichloro(1,2-dimethoxyethane)bis(tosylimido)molybdenum(VI), a versatile nitrene transfer reagent. 1645 73