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Query: UMLS:C0271276 (Hudson)
 1,066 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

Nitrate, sulfate, and carbonate were used as electron acceptors to examine the anaerobic biodegradability of chlorinated aromatic compounds in estuarine and freshwater sediments. The respective denitrifying, sulfidogenic, and methanogenic enrichment cultures were established on each of the monochlorinated phenol and monochlorinated benzoic acid isomers, using sediment from the upper (freshwater) and lower (estuarine) Hudson River and the East River (estuarine) as source materials. Utilization of each chlorophenol and chlorobenzoate isomer was observed under at least one reducing condition; however, no single reducing condition permitted the metabolism of all six compounds tested. The anaerobic biodegradation of the chlorophenols and chlorobenzoates depended on the electron acceptor available and on the position of the chlorine substituent. In general, similar activities were observed under the different reducing conditions in both the freshwater and estuarine sediments. Under denitrifying conditions, degradation of 3- and 4-chlorobenzoate was accompanied by nitrate loss corresponding reasonably to the stoichiometric values expected for complete oxidation of the chlorobenzoate to CO2. Under sulfidogenic conditions, 3- and 4-chlorobenzoate, but not 2-chlorobenzoate, and all three monochlorophenol isomers were utilized, while under methanogenic conditions all compounds except 4-chlorobenzoate were metabolized. Given that the pattern of activity appears different for these chlorinated compounds under each reducing condition, their biodegradability appears to be more a function of the presence of competent microbial populations than one of inherent molecular structure.
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PMID:Influence of alternative electron acceptors on the anaerobic biodegradability of chlorinated phenols and benzoic acids. 847 90

Drifting snow samples were collected at Asuka Station (71 degrees 32'S, 24 degrees 08'E, 930 m above sea level) over a period from July to December 1991; 36 elements (including Na, Mg, K, Ca, Fe, Al, Li, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Se, Rb, Sr, Cd, Pb, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Th) in snow were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) by direct sample introduction. Concentrations of Cl-, NO3-, and SO(4)2- in the snow were also determined by ion chromatography. In late September to early October, there was a pronounced peak concentration of most of the elements together with non-sea salt sulfate. Enrichment factor analyses suggest that Na, Mg, Ca, K, and Sr are of marine origin and Al, Fe, Mn, Rb, Cr, Ni, Ga, V, and all the rare earth elements are of crustal origins. Volcanic eruption of Mt. Pinatubo (June 1991) and Mt. Hudson (August 1991) could be the reason for the precipitation of Pb, Cd, Cu, Zn, and Se together with non-sea salt sulfates in the austral spring at Asuka Station.
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PMID:Springtime peaks of trace metals in Antarctic snow. 928 1

Rivers receive a significant fraction of the anthropogenic nitrogen applied to the world's watersheds. Environmental conditions in rivers should be conducive to the formation of N2O, and recent models suggest that rivers could constitute up to 25% of the anthropogenic contribution of N2O to the atmosphere. Few direct measurements exist, however, of N2O flux between rivers, especially large rivers, and the overlying atmosphere. We measured the concentration of N2O over a 2-year period in a large, tidal, freshwater river. We coupled these measurements with a physical model of gas exchange based on inert gas tracer additions to this river and computed the flux of N2O to the atmosphere. The tidal, freshwater Hudson River is persistently supersaturated in N2O with respect to the atmosphere, with average partial pressure of N2O (pN2O) of 0.58 muatm or about 185% of atmospheric equilibrium. At all times during a 2-year cycle and at all locations sampled along a 200 km stretch of the river, the river was a net source of N2O to the atmosphere. We estimate that the tidal, freshwater Hudson River contributes 0.056 g of N2O-N m(-2) to the atmosphere annually. Despite relatively high concentrations of NO3 in the Hudson River, the tidal, freshwater river is a minor source of N2O in comparison to other rivers for which estimates exist and to components of its own watershed. The river itself accounts for only 1.3% of the total N2O contribution to the atmosphere that occurs in the Hudson watershed.
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PMID:Emissions of nitrous oxide (N2O) from a tidal, freshwater river, the Hudson River, New York. 1134 46

Narthecium ossifragum (L.) Hudson was subjected to artificial deposition events in three experiments. In the first, a laboratory experiment, 1.0 m nitrate significantly decreased the growth of Narthecium, and the shoot and root nitrogen content of the plants was increased in all enhanced nitrogen treatments. In the second experiment, solutes were applied in situ to a relatively unpolluted upland ombrotrophic mire at concentrations measured in cloud water at a polluted site in England. There was no effect on Narthecium tissue nitrogen concentration due to either ammonium or nitrate applied alone but the shoot nitrogen was significantly increased when the ammonium and nitrate were applied in combination. In the third experiment, a piece of upland ombrotrophic mire from a relatively unpolluted site in North Wales was transplanted to a polluted site in northern England. After two years both the shoots and roots of Narthecium present in the mire showed a higher nitrogen concentration in the transplant compared with the control. These data show that nitrogen supply in the southern Pennines is supra-optimal for Narthecium, which implies that in such situations it (and other species with a similar ecological strategy) would be out-competed by more vigorous species. The data from the field experiment at the relatively unpolluted site imply that even there, nitrogen supply is close to supra-optimal for Narthecium.
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PMID:An experimental investigation of the effects of nitrogen deposition to Narthecium ossifragum. 1509 85

Hudson River sediment microcosms from Piles Creek (PC), Piermont Marsh (PM), and Iona Island (II) were amended with approximately 100mM nitrate or sulfate to stimulate anaerobic bioremediation. Nitrate and sulfate decreased over two years of field incubation and the fraction of these losses due to diffusion to the water column was predicted using Fick's law. Apparent diffusion (D(app)) values of 1-4x10(-10)m(2)s(-1) predicted the majority of loss/gain from/to the sediments by 700 d, but not at all times. Effective diffusion (D(eff)) values predicted by the porosity function (D(eff)=D(mol)epsilon(4/3)) were larger than those observed in the field, and field data indicates a cube power relationship: D(eff)=D(mol)epsilon(3). D(app) greatly increased in surficial layers at PM and PC in year two, suggesting that bioadvection caused by bioturbating organisms had occurred. The effects of bioturbation on transport to/from the sediments are modeled, and results can be applied to various sediment treatment scenarios such as capping.
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PMID:Diffusional losses of amended anaerobic electron acceptors in sediment field microcosms. 2039 75

Biogeochemical functioning of ecosystems is central to nutrient cycling, carbon balance, and several ecosystem services, yet it is not always clear why levels of function might vary among systems. Wetlands are widely recognized for their ability to alter concentrations of solutes and particles as water moves through them, but we have only general expectations for what attributes of wetlands are linked to variability in these processes. We examined changes in several water quality variables (dissolved oxygen, dissolved organic carbon, nutrients, and suspended particles) to ascertain which constituents are influenced during tidal exchange with a range of 17 tidal freshwater wetlands along the Hudson River, New York, USA. Many of the constituents showed significant differences among wetlands or between flooding and ebbing tidal concentrations, indicating wetland-mediated effects. For dissolved oxygen, the presence of even small proportional cover by submerged aquatic vegetation increased the concentration of dissolved oxygen in water returned to the main channel following a daytime tidal exchange. Nitrate concentrations showed consistent declines during ebbing tides, but the magnitude of decline varied greatly among sites. The proportional cover by graminoid-dominated high intertidal vegetation accounted for over 40% of the variation in nitrate decline. Knowing which water-quality alterations are associated with which attributes helps suggest underlying mechanisms and identifies what functions might be susceptible to change as sea level rise or salinity intrusion drives shifts in wetland vegetation cover.
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PMID:Ecosystem attributes related to tidal wetland effects on water quality. 2360 Feb 46