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Target Concepts:
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Query: UMLS:C0267964 (
PAA
)
2,561
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
FT-IR and FT-Raman spectroscopic methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic acid)/sodium salt of carboxymethyl starch (
PAA
/CMS-Na) applied as a binder for moulding sands. The cross-linking was performed by chemical methods by introducing cross-linking substances with Ca(2+) ions or glutaraldehyde and by physical way, applying the microwave radiation. It was found that Ca(2+) ions cause formation of cross-linking ionic bonds within carboxyl and carboxylate groups.
Glutaraldehyde
generates formation of cross-linking bonds with hemiacetal and acetal structures. Whereas in the microwave radiation field, due to dehydration, lattices are formed by anhydride bonds.
...
PMID:FT-IR and FT-Raman studies of cross-linking processes with Ca(2+) ions, glutaraldehyde and microwave radiation for polymer composition of poly(acrylic acid)/sodium salt of carboxymethyl starch--part I. 2512 42