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 15,125 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

A method has been developed which allows the incubation of alveolar macrophages as weakly affixed monolayers in siliconized glass dishes. Without vigorous mechanical agitation and without using proteolytic enzymes, these cells were subsequently transferred to cuvettes where the zymosan-stimulated chemiluminescence of the suspended cells was measured. In vitro incubations of activated rabbit alveolar macrophage monolayers with airborne dusts from four West German sites (1 to 200 micrograms/10(6) cells), fly ash fractions of a special waste incinerator at Hamburg (50 to 1,000 micrograms/10(6) cells), and quartz dust DQ 12 (5 to 200 micrograms/10(6) cells) resulted in a dose- dependent depression of the zymosan-stimulated chemiluminescence. The depression of chemiluminescence was correlated with particle numbers, estimated dust surface, and antimony and lead masses of the dusts to which the cells were exposed. Cytotoxicity was better correlated with these parameters than with dust mass.
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PMID:Zymosan-induced chemiluminescence of alveolar macrophages: depression by inorganic dust constituents. 189 16

A study was carried out for the purpose of obtaining and characterizing a protein concentrate obtained from defatted oil palm cake using alkaline extraction, and compare it with a commercial soy meal. The oil palm cake came from a national industry as a subproduct of the oil extraction of the palm kernels. The moisture, protein, fat, crude fiber and ash content of the oil palm was then determined. The optimum conditions for extraction and precipitation of the proteins were selected. These were the following: extraction at pH, 11.4; adding NaOH 0.06 M solvent; a meal/solvent relation of 1:20 g/ml and extraction time, 20 minutes with magnetic agitation, and precipitation at pH 5.3. The protein concentrate obtained contained: 66.50% protein; 0.07% fat, 0.90% crude fiber, and 3.20% ashes. Then the following functional properties were analyzed: solubility, according to the pH; water absorption (250); oil absorption (175); emulsion activity (27.2), and stability (13.6). The author concludes that the protein concentrate has good water and oil absorption when compared to soymeal; the emulsion, however, was found to be unstable to heat.
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PMID:[Protein concentrate of African oil palm (Elaesis guineensis, Jacquin), extraction process and functional properties]. 384 56

The purpose of this study was to evaluate the effect of pH on the extraction of protein nitrogen from Atriplex lampa leaves (Moquin) Dietrich. The chemical characterization of the dry matter indicated the following (g/100 g): protein, 26.93; ash, 21.80; ether extract, 4.65; dry matter, 37.30; sodium, 6.05; and calcium, 0.41. Non-critical values were obtained for saponins and nitrates. The high concentration of oxalic acid (8.52 g/100 g), together with elevated salt content account for the low palatability of the studied species. In order to determine the parameters needed to improve the extraction in protein nitrogen from leaves, fresh material was macerated with 2% sodium metasulfite, followed by pulping with a hand-driven grinder. Extractions were performed at different pH values (2-12) adjusting the value with 5N HCL or NaOH, with agitation followed by centrifugation and pressing. Supernatants were collected and kept. The last extraction was performed with Tween 20 in order to obtain maximum nitrogen recovery from the residue cake. Highest extraction (41.23%) was obtained at pH 10 with a 1:5 ratio (leaf: deionized water, w/v). It is proposed that this regional natural resource may be used to elaborate a protein concentrate, which can be made more palatable by decreasing potassium and sodium salt content with the use of membrane technology.
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PMID:Protein extraction from Atriplex lampa leaves: potential use as forage for animals used for human diets. 1071 6

In the present paper, boron removal from aqueous solutions by adsorption was investigated. Fly ash particle size used in adsorption experiments was between 250 and 400 microm. During the experimental part of this study, the effect of parameters such as pH, agitation time, initial boron concentration, temperature, adsorbent dosage and foreign ion on boron removal were observed. In addition, adsorption kinetics, adsorption isotherm studies and column studies were made. Maximum boron removal was obtained at pH 2 and 25 degrees C. Thermodynamic parameters such as change in free energy (DeltaG degrees), enthalpy (DeltaH degrees), entropy (DeltaS degrees) were also determined. As a result of the kinetic studies, it was observed that the adsorption data conforms to the second degree kinetics model. In the isotherm studies, Langmuir and Freundlich isotherm models were applied and it was determined that the experimental data conformed to Langmuir isotherm model. Batch adsorbent capacity (q(o)) was calculated as 20.9 mg/g. The capacity value for column study was obtained by graphical integration as 46.2 mg/g. The Thomas and the Yoon-Nelson models were applied to experimental data to predict the breakthrough curves and to determine the characteristics parameters of the column useful for process design.
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PMID:Adsorption of boron from aqueous solutions using fly ash: batch and column studies. 1609 59

The production of pellets of the fungus Agaricus campestris NRRL 2334 was studied in submerged fermentation with peat extract as the main substrate source. Pellets up to 6 mm in diameter were obtained when the peat extract was diluted to reduce the concentration of growth inhibitors. Yeast extract and yeast extract plus glucose were the most effective nutrient supplements in the diluted peat extract media and stimulated the formation of large pellets which contained 44.4% crude protein, 2.8% fat, and 9% ash (dry weight basis). No solid supports were required for the growth of the pellets. The effects on the growth morphology of several dilution ratios of the peat extract, rates of agitation and aeration, and time were investigated.
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PMID:Growth of Agaricus campestris NRRL 2334 in the Form of Pellets. 1634 18

Sorptive potential of selected agricultural waste materials i.e. rice (Oryza sativa) bran (RB), bagasse fly ash (BFA) of sugarcane (Saccharum officinarum), Moringa oleifera pods (MOP) and rice husk (RH) for the removal of methyl parathion pesticide (MP) from surface and ground waters has been investigated. Optimization of operating parameters of sorption process, i.e. sorbent dose, agitation time, pH, initial concentration of sorbate, and temperature have been studied. The sorption data fitted to Freundlich, Langmuir and Dubinin-Radushkevich (D-R) sorption isotherms. The maximum capacities of RB, BFA, MOP and RH for MP were calculated to be 3.6+/-0.8, 5.3+/-1.4, 5.2+/-1.5 and 4.7+/-1.0 mmolg(-1) by Freundlich, 0.39+/-0.009, 0.39+/-0.005, 0.36+/-0.004 and 0.35+/-0.008 mmolg(-1) by Langmuir and 0.9+/-0.08, 1.0+/-0.10, 1.0+/-0.10 and 0.9+/-0.07 mmolg(-1) by D-R isotherms respectively, employing 0.1g of each sorbent, at pH 6, 90 min agitation time and at 303 K. Application of first order Lagergren and Morris-Weber equations to the kinetic data yielded correlation coefficients, close to unity. Thermodynamic parameters of sorption process, i.e. DeltaH, DeltaS and DeltaG were computed and their negative values indicated the exothermic and spontaneous nature of sorption process. The pesticide may be stripped by sonication with methanol, making the regeneration and reutilization of sorbents promising. The sorbents investigated exhibited their potential applications in water decontamination, treatment of industrial and agricultural waste waters.
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PMID:Low cost sorbents for the removal of methyl parathion pesticide from aqueous solutions. 1710 16

Studies on the utilization of low cost adsorbents for removal of heavy metals from wastewaters are gaining attention. Fired coal fly ash, a solid by-product that is produced in power plants worldwide in million of tonnes, has attracted researchers' interest. In this work, fly ash was shaped into pellets that have diameter in-between 3-8mm, high relative porosity and very good mechanical strength. The pellets were used in adsorption experiments for the removal of copper and cadmium ions from aqueous solutions. The effect of agitation rate, equilibration time, pH of solution and initial metal concentration were studied. The adsorption of both cations follows pseudo-second order kinetics reaching equilibrium after an equilibration time of 72 h. The experimental results for copper and cadmium adsorption fit well to a Langmuirian type isotherm. The calculated adsorption capacities of pellets for copper and cadmium were 20.92 and 18.98 mg/g, respectively. Desorption experiments were performed in several extraction media. The results showed that both metals were desorbed substantially from pellets under acidic solutions. For this reason, metal saturated pellets were encapsulated in concrete blocks synthesized from cement and raw pulverized fly ash in order to avoid metal desorption. The heavy metals immobilization after encapsulation in concrete blocks was tested through desorption tests in several aqueous media. The results showed that after 2 months in acidic media with pH 2.88 and 4.98 neither copper nor cadmium were desorbed thus indicating excellent stabilization of heavy metals in the concrete matrix. As a conclusion, the results showed that fly ash shaped into pellets could be considered as a potential adsorbent for the removal of copper and cadmium from wastewaters. Moreover, the paper proposes an efficient and simple stabilization process of the utilized adsorbents thus guarantying their safe disposal in industrial landfills and eliminating the risk of pollution for groundwater and other natural water receivers.
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PMID:Copper and cadmium adsorption on pellets made from fired coal fly ash. 1741 61

Adsorption kinetic and equilibrium studies of three reactive dyes namely, Remazol Brillant Blue (RB), Remazol Red 133 (RR) and Rifacion Yellow HED (RY) from aqueous solutions at various initial dye concentration (100-500 mg/l), pH (2-8), particle size (45-112.5 microm) and temperature (293-323 K) on fly ash (FA) were studied in a batch mode operation. The adsorbent was characterized with using several methods such as SEM, XRD and FTIR. Adsorption of RB reactive dye was found to be pH dependent but both RR and RY reactive dyes were not. The result showed that the amount adsorbed of the reactive dyes increased with increasing initial dye concentration and contact time. Batch kinetic data from experimental investigations on the removal of reactive dyes from aqueous solutions using FA have been well described by external mass transfer and intraparticle diffusion models. It was found that external mass transfer and intraparticle diffusion had rate limiting affects on the removal process. This was attributed to the relatively simple macropore structure of FA particles. The adsorption data fitted well with Langmuir and Freundlich isotherm models. The optimum conditions for removal of the reactive dyes were 100mg/l initial dye concentration, 0.6g/100ml adsorbent dose, temperature of 293 K, 45 microm particle size, pH 6 and agitation speed of 250 rpm, respectively. The values of Langmuir and Freundlich constants were found to increase with increasing temperature in the range 135-180 and 15-34 mg/g for RB, 47-86 and 1.9-3.7 mg/g for RR and 37-61 and 3.0-3.6 mg/g for RY reactive dyes, respectively. Different thermodynamic parameters viz., changes in standard free energy, enthalpy and entropy were evaluated and it was found that the reaction was spontaneous and endothermic in nature.
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PMID:Adsorption of reactive dyes from aqueous solutions by fly ash: kinetic and equilibrium studies. 1757 38

A new adsorbent was developed from waste ash resulting from municipal solid waste and coal co-combustion power plant. The ash was firstly subjected to hydrothermal treatment for zeolite synthesis, and then modified with iron(II) ions by agitation (ISZ) or ultrasonic (UISZ) treatment. The effect of operating factors such as pH, contact time, initial As(V) concentration and adsorbent dosage was investigated and the optimum operating conditions were established. The adsorption capacity for As(V) onto UISZ and ISZ were 13.04 and 5.37 mg g(-1), respectively. The adsorption isotherm data could be well described by Langmuir isotherm model. The optimum initial pH values for As(V) removal were 2.5 and 2.5-10.0 by ISZ and UISZ, respectively. The results indicated that ultrasound treatment scattered the particles of the adsorbent uniformly, which was in favor of impregnating iron ions into pores. Leaching of hazardous elements from the used adsorbents was very low. Accordingly, it is believed that the adsorbents developed in this study are environmentally acceptable and industrially applicable for utilization in arsenic-containing wastewater treatment.
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PMID:An effective adsorbent developed from municipal solid waste and coal co-combustion ash for As(V) removal from aqueous solution. 1835 54

The effect of whey protein concentrate (WPC) and gum tragacanth (GT) as fat replacers on the chemical, physical, and microstructural properties of nonfat yogurt was investigated. The WPC (7.5, 15, and 20 g/L) and GT (0.25, 0.5, 0.75, and 1 g/L) were incorporated into the skim milk slowly at 40 to 45 degrees C with agitation. The yogurt mixes were pasteurized at 90 degrees C for 10 min, inoculated with 0.1% starter culture, and incubated at 42 degrees C to pH 4.6, then refrigerated overnight at 5 degrees C. A control nonfat yogurt and control full fat yogurt were prepared as described, but without addition of WPC and GT. Increasing amount of WPC led to the increase in total solids, total protein, acidity, and ash content, whereas GT did not affect chemical parameters. Increasing WPC caused a more compact structure consisting of robust casein particles and large aggregates. Firmness was increased and susceptibility to syneresis was decreased as WPC increased. No significant difference was observed for firmness and syneresis of yogurt fortified with GT up to 0.5 g/L compared with control nonfat yogurt. Increasing the amount of gum above 0.5 g/L produced softer gels with a greater tendency for syneresis than the ones prepared without it. Addition of GT led to the coarser and more open structure compared with control yogurt.
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PMID:Whey protein concentrate and gum tragacanth as fat replacers in nonfat yogurt: chemical, physical, and microstructural properties. 1856 11


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