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Query: UMLS:C0205700 (ash)
15,125 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

Relative biological values (BV) of 36 feed phosphates were determined with female turkeys in bioassays of 21-day duration using three response criteria: weight gain, tibia ash percentage, and gain:feed ratio. Calcium phosphate, dibasic dihydrate (United States Pharmacopeia) was the reference standard. Nine mono-dicalcium phosphates (M-DCP, 21.0% phosphorus), 13 di-monocalcium phosphates (D-MCP, 18.5% phosphorus), and 14 defluorinated phosphates (DFP, 18.0% phosphorus) were evaluated. The average relative BV for M-DCP, D-MCP, and DFP samples were 97.6, 94.6, and 90.8%, respectively. Solubility of phosphates was determined by four recognized methods. The solvents were water, .4% HCl, 2.0% citric acid (CA), and neutral ammonium citrate (NAC). Water solubility of M-DCP samples was greater (67.5%) than that of D-MCP (38.8%) and DFP (8.9%) samples. Correlation of water solubility of phosphates to their relative BV was quite low, and water solubility was a poor indicator of BV. When .4% HCl was the solvent, correlation coefficients (r) were .55, .33, and .72 for M-DCP, D-MCP, and DFP, respectively. Based on these results and prediction equations, .4% HCl solubility would be inappropriate for estimating BV of M-DCP and D-MCP samples. Solubility of feed phosphates (mainly D-MCP and DFP) in 2.0% CA or NAC was positively correlated with BV; the r values were .87 to .95. Both of these solubility tests provided a good index of BV. However, it would seem inappropriate and risky to replace bioassays totally with these tests. Feed phosphate users could perform either the 2.0% CA or NAC solubility test easily as a screen for BV along with other quality control procedures (i.e., phosphorus, calcium, sodium, and fluoride determinations).
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PMID:Correlation of biological value of feed phosphates with their solubility in water, dilute hydrogen chloride, dilute citric acid, and neutral ammonium citrate. 147 May 90

The apparent digestibility of a molassed, chaffed grass hay/straw mixture was determined using four mature horses (mean weight 606 kg). Animals were stalled individually and kept on rubber mats. A preliminary feeding period of 18 days was followed by a 10 day collection period. Chromium-mordanted hay was given before the first feed at 08.00 h and subsequent meals were at 12.00, 16.00 and 20.00 h. On Days 3 and 10 of the collection, all faeces were sampled over a 24 h period. In addition, throughout the 10 day collection, faecal material was sampled at 10.00 and 16.00 h. The mean (+/- se) chromium recovery was 96.5 per cent +/- 0.76 and the hay/straw mixture contained 7 MJDE/kg dry matter and 15.1 g DCP/kg dry matter. There was no significant difference between the methods used to estimate apparent digestibility although chromium measurements consistently underestimated whilst acid-insoluble ash consistently overestimated digestibility values. There was a large variation in faecal chromium concentration for each horse over a 24 h period compared to acid-insoluble ash concentrations and, consequently, indirect estimates of apparent digestibility of nutrients in the equine are prone to large errors if chromium is used as a marker. If total faecal collection is impractical, acid-insoluble ash is the preferred indirect marker for the estimation of apparent digestibility coefficients for nutrients in horses.
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PMID:A comparison between chromium-mordanted hay and acid-insoluble ash to determine apparent digestibility of a chaffed, molassed hay/straw mixture. 231 76

Two experiments were conducted to determine the relative biological values (BV) of phosphorus in feed phosphates. Experiment 2 was a replicate of Experiment 1, except that an additional phosphate source was tested. Within experiments, each treatment was replicated twice. Each pen contained eight broiler cockerels. The experimental diets were composed primarily of corn and soybean meal. The reference phosphate [anhydrous, reagent-grade, dibasic calcium phosphate (AR-DCP)] was added to supply five levels of phosphorus. Each phosphate supplement was added to supply two levels of phosphorus. A regression equation was calculated based on logarithm g, nonphytate phosphorus per kilogram of diet versus the percentage of bone ash from chicks fed diets containing AR-DCP. Nonphytate phosphorus equivalents were calculated using the percentage of bone ash from chicks fed the test phosphates. The biological values of the test phosphates were determined as nonphytate phosphorus equivalents, minus the nonphytate phosphorus in the basal diet, divided by the amount of supplemental phosphorus. The BV obtained for the commercial phosphates in Experiments 1 and 2 were: dibasic calcium phosphate, 106 and 104; monobasic calcium phosphate. 102 and 104; defluorinated phosphate (DFP)-1, 88 and 90; and DFP-2, 100.
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PMID:The relative biological value of feed phosphates for chicks. 232 May 22

A study was conducted to determine the relative biological value (RBV) of phosphorus from two bone-precipitated dicalcium phosphates (DCP-BP) in turkey starter diets. An estimated 40,000 metric tons of DCP-BP are produced annually in the United States as a by-product of gelatin production. The two DCP-BP sources were compared to commercial feed phosphates. Two bioassay experiments of 21-d duration were conducted with female turkeys. Phosphate sources were each fed at three levels (.18, .24, and .36% added total phosphorus) in a corn-soybean meal diet. Calcium level was maintained constant at 1.0% in all diets by adjusting the level of ground limestone. Four replicate pens of six poults were randomly assigned at 1 d of age to each level of each phosphorus source in each bioassay. The reference standard was United States Pharmacopeia (USP) grade calcium phosphate, dibasic dihydrate. Data representing three response criteria (weight gain, gain:feed ratio, and tibia ash percentage at 21 d) were combined to calculate a biological value (BV) for each test source and the reference standard phosphate. A RBV was then computed for each test source. The RBV of the two DCP-BP sources were 98.8 and 99.1, as compared to 100.0 for the reference standard, and 86.7, 87.1, and 88.4 for three commercial, thermochemically produced defluorinated phosphates. The RBV of one commercial mono-dicalcium phosphate, and three di-monocalcium phosphates were: 96.4, and 91.2, 94.7, and 101.5, respectively. The two DCP-BP sources compared favorably to commercial feed phosphates, and would be satisfactory supplements in diets for starting chicks, poults, pigs, and other species.
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PMID:Biological value of bone-precipitated dicalcium phosphate in turkey starter diets. 816 58

A feeding trial was performed using 4 x 60 day-old chickens (Ross 208 cockerels) raised up to 42 days of age to determine whether exogenous phytase addition increases phosphorus utilisation by broiler chickens, and to assess its effects on some production traits as well as on the ash content and mechanical stability of the tibia. The chickens' feed consisted of maize, wheat, soybean meal, fish meal, yeast, and fat powder. The basic feed was supplemented with inorganic phosphorus in groups A and B. In groups C and D, the amount of the inorganic phosphorus supplement (DCP) was decreased by 50%, at the same calcium/phosphorus ratio. The 50% reduction of inorganic phosphorus supplementation represents a 20% decrease of total phosphorus. To the diets of groups B and D a phytase enzyme preparation (Phytase Novo CT) was added. The calculated exogenous phytase activity was 600 FYT/kg feed. The decrease of inorganic phosphorus did not cause significant differences in the daily weight gain but lowered the feed conversion rate by 10%. Calcium and phosphorus excretion decreased by 18% and 15%, and the breaking strength of the tibia was also lower. Phytase supplementation of the feed at a lower rate of inorganic phosphorus supplementation did not cause changes in the body weight gain but improved the feed conversion rate by 5.6%. Phosphorus and calcium output decreased by 21% and 11%, respectively, but chemical composition and mechanical stability of the tibia were unaltered.
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PMID:Effects of phytase supplementation on calcium and phosphorus output, production traits and mechanical stability of the tibia in broiler chickens. 970 26

Fly ash from coal-fired thermal power plants can be used for the removal of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP) with enthalpy changes of about -3 kcal/mol. The amounts of 2-CP and 2,4-DCP removed are affected by the pH value of the solution. The efficiency of removal improves when the pH value is less than the pK(a) values of 2-CP and 2,4-DCP, respectively. The adsorbed amount of chlorophenol by fly ash is also affected by particle diameter, carbon content, and the specific surface area of the ash used in this study. As expected, more adsorption takes place with fly ash of higher carbon content and larger specific surface area. Moreover, the adsorbed amount of chlorophenol is not influenced by the matrix in the wastewater, as shown by studying the removal of 2-CP and 2, 4-DCP in wastewater from a synthetic fiber plant. Chlorophenols in the wastewater were also removed efficiently through a fly ash column, with breakthrough times being inversely proportional to flow rates.
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PMID:Removal of chlorophenols from aqueous solution by fly ash. 1093 36

In two fattening trials (in each 100 broilers kept in four groups with 25 animals) as well as in a balance trial (four groups with four broilers in a group) the effects of inorganic phosphorus sources [monocalcium phosphate (MCP), dicalcium phosphate (dihydrate; DCP) and defluorinated phosphate (DFP)] in broiler diets were examined. The four diets contained up to 9 g calcium and 6 g phosphorus per kg and comparable energy and nutrient contents. Controls were fed a commercial diet with Ca-Na-phosphate as inorganic phosphorus source supplemented by phytase. In both fattening trials body weight gain, feed consumption and feed conversion were proved as well as the calcium and phosphorus levels in serum, the breaking strength of tibia or humerus and the femur mineralization (ash content in the fat free dry matter). Furthermore, in the balance trial the retention of calcium and phosphorus was determined by calculation (intake minus excretion) as well as by analysis of body composition. On a high performance level (that was only slightly influenced by the different treatments), the addition of DFP resulted in significantly reduced phosphorus availability (estimated by analysis of the whole carcass: control/MCP/DCP/DFP: 48.6/46.0/45.7/35.5%). The significantly reduced phosphorus level in serum (1.77 +/- 0.20/1.77 +/- 0.24/1.73 +/- 0.28 1.34 +/- 0.33 mmol/l) indicates the lower phosphorus retention in broilers given DFP. Furthermore, the crude ash content (582 +/- 17.6/580 +/- 18.6/563 +/- 15.2/547 +/- 29.7 g/kg fat free DM) and the breaking strength of bones (in right tibia in trial 2: 232 +/- 82.4/227 +/- 51.5/232 +/- 41.7/196 +/- 655 N) were lowest when given DFP. For diagnostic purposes it is of special interest that the phosphorus levels in the serum reflected markedly the different concentrations of available phosphorus in the diet.
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PMID:Effects of different phosphorus sources in the diet on bone composition and stability (breaking strength) in broilers. 1578 83

Chlorophenols are one of the most important groups of priority pollutants, due to their high toxicity, mutagenicity and carcinogenicity. Although activated carbon has been the preferred choice for the removal of such pollutants from wastewaters, the search for cheaper alternative sorbents became common in the last years. Fly ash, a by-product from coal burning power plants, has a surface composition that may enable the sorption of specific organic compounds. Therefore, this feasibility study presents the optimization of the operating parameters of a fixed-bed column containing fly ash particles, percolated by aqueous solutions of 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) with concentrations of 1 and 100 microg/ml. Both chlorophenols were analysed by gas chromatography with electron capture detection (GC-ECD), after solid-phase microextraction (SPME), with limits of detection (LODs) of 7.28 microg/l for 2,4-DCP and 1.76 microg/l for PCP. Removal efficiencies above 99% were obtained for an initial concentration of 10 microg/ml of chlorophenols. Column saturation was achieved after 7h of continuous operation for 2,4-DCP and 10h for the PCP for feed levels of 10 microg/ml. Fly ash exhibited more affinity towards the sorption of PCP, in comparison to 2,4-DCP.
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PMID:Removal of 2,4-dichlorophenol and pentachlorophenol from waters by sorption using coal fly ash from a Portuguese thermal power plant. 1714 54

This study focuses on the homogeneous gas-phase formation of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) from the 2,4,6-trichlorophenol (2,4,6-TCP) and 2,4-dichlorophenol (2,4-DCP) precursors, which were found both in the gas phase and in the fly ash samples as the dominating chlorophenol congeners in municipal waste incinerators (MWIs). Molecular orbital theory calculations have been performed for the formation mechanism. The geometrical parameters and vibrational frequencies of all the stationary points were calculated at the MPWB1K level with the 6-31+G(d,p) basis set. Single-point energy calculations were carried out at the MPWB1K/6-311+G(3df,2p) level of theory. Canonical variational transition-state (CVT) theory with small curvature tunneling (SCT) contribution was used to predict the rate constants of crucial elementary steps over the temperature range of interest (600-1200 K). The rate-temperature formulas were fitted for the first time. The pre-exponential factor, the activation energy, and the rate constants are reported. This study shows that at least one chlorine substituent in the ortho position is needed for the formation of PCDDs from the condensation of chlorophenols. The results presented here should help to clarify and detail the formation mechanism of PCDD/PCDFs (PCDD/Fs for short) from chlorophenol precursors in real waste combustion.
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PMID:Quantum chemical and kinetic study on dioxin formation from the 2,4,6-TCP and 2,4-DCP precursors. 2038 Apr 13

The main objective of this study was to compare different bone measurements in response to supplements of mineral P sources. Comparisons were also made with P retention and digestibility responses determined in a companion study and with blood inorganic phosphate (P(i)) responses. A corn-soybean meal-based basal diet was used (0.35% total P on DM basis). Anhydrous monosodium phosphate (MSP(a)) or anhydrous dibasic calcium phosphate (DCP(a)) was supplemented to increment the P concentration by 0.08%, 0.16%, or 0.24%. Each of the 7 diets was fed for 10 d starting 11 d (period 1) or 25 d posthatch (period 2). Bone ash and P were determined, and density criteria were measured using quantitative computed tomography. Responses were evaluated and compared based on linear regression analysis. In general, responses to MSP(a) had a greater slope than DCP(a) for all criteria studied. In period 1, differences between the slopes were significant (P < 0.05) for almost all bone criteria. In period 2, the slopes significantly differed for the amounts of ash and P of all bones studied, for tibia, tarsometatarus, and foot ash percentage, for total and cortical density of tibiae, but not for the other criteria. For the different bones, the ratio of slopes for MSP(a) and DCP(a) was very similar based on the amount of ash in both periods. Foot ash proved to be as sensitive as tibia ash for evaluation of mineral P sources in both periods. Ninety-four percent of the variance of the corticalis content based on quantitative computed tomography measurements could be explained by the amount of tibia ash in period 1. Blood serum P(i) and BW gain were not suitable for P evaluation. We concluded that the ranking of mineral P sources based on bone criteria differed from the ranking that was based on P retention or prececal digestibility. This underlines the need for developing a standard protocol of determination of available P in poultry.
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PMID:Comparison and evaluation of bone measurements for the assessment of mineral phosphorus sources in broilers. 2291 55


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