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Query: UMLS:C0033036 (APC)
10,214 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

Multiwalled carbon nanotubes (MWCNTs) were purified by mixed HNO3/H2SO4 solution and were employed as adsorbents to study adsorption kinetics and thermodynamics of trihalomethanes (THMs) from chlorinated drinking water. The amount of THMs adsorbed onto CNTs decreased with a rise in temperature and high adsorption capacities were found at 5 and 15 degrees C. Under the same conditions, the purified CNTs possess two to three times more adsorption capacities of CHCl3, which accounts for a major portion of THMs in the chlorinated drinking water, than the commercially available PAC suggesting that CNTs are efficient adsorbents. The thermodynamic analysis revealed that the adsorption of THMs onto CNTs is exothermic and spontaneous.
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PMID:Adsorption thermodynamic and kinetic studies of trihalomethanes on multiwalled carbon nanotubes. 1683 63

The grafting of amino and carboxylic acid groups on cellulose increased La(III) sorption efficiency of cellulose: maximum sorption capacity increased from 38mgLag-1 for cellulose to 101 and 170mgLag-1 for amino derivative (PAC) and amino-carboxylic derivative (PCMC). Langmuir equation successfully fits sorption isotherms while uptake kinetics are effectively modeled using the pseudo-first order rate equation (though resistance to intraparticle diffusion plays a significant role in the control of metal recovery). Uptake equilibrium occurred within 150-180min. The thermodynamic study shows that the reaction is spontaneous, endothermic and entropic. Nitric acid solutions (0.5M concentration) can be efficiently used for metal recovery and sorbent can be recycled for at least 5 cycles with limited decrease in sorption performance for the three sorbents. The materials were characterized by elemental analysis, acid-base titration, FTIR spectrometry, x-ray diffraction analysis, X-ray photoelectron spectroscopy, SEM-EDX analysis and also by TGA.
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PMID:Synthesis and characterization of poly(carboxymethyl)-cellulose for enhanced La(III) sorption. 2798 99