Gene/Protein
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Enzyme
Compound
Pivot Concepts:
Gene/Protein
Disease
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Target Concepts:
Gene/Protein
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Query: UMLS:C0027960 (
mole
)
21,279
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
Synopsis Model systems composed of
2-hydroxycyclohexanone
and ammonium acetate in a
mole
ratio of 1 to 3 were set up to study the formation of octahydrophenazine (OHP). Octahydrophenazine and an intermediate were isolated and characterized by GC/MS (El and Cl). This intermediate was the condensation product between a molecule of
2-hydroxycyclohexanone
and 2-amino-cyclohexanone via the SchifT base formation mechanism. A larger amount of the intermediate than of OHP was found in the solvent system containing less than 20% ethanol, the relative proportion of the intermediate decreasing as the percentage of ethanol was increased. The formation mechanism for OHP is proposed.
...
PMID:Mechanistic Studies of Octahydrophenazine Formation from a 2-Hydroxycyclohexanone/Ammonium Acetate Model System in Ethanol. 2729 57
