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Query: UMLS:C0002986 (
Fabry
)
5,646
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
Rotational spectra have been assigned for five isotopic species of the OC...
HBr
hydrogen-bonded molecular complex by using pulsed microwave Fourier transform spectroscopy in a
Fabry
-Perot cavity and a pulsed supersonic nozzle as the molecular source. The rotational constants, centrifugal distortion constants, Br nuclear-quadrupole-coupling constants, and Br spin-rotation constants were determined and from them, the vibrationally averaged structure of OCHBr was derived. This structure is consistent with a linear geometry at equilibrium and an atomic arrangement as written above. The intermolecular potential binding CO to
HBr
is discussed.
...
PMID:Microwave spectrum and molecular structure of the carbon monoxide-hydrogen bromide molecular complex. 1659 81
Suitable bands of common gases have been tabulated and remeasured wherever necessary from 2 to 16 microns to obtain an accuracy of about 0.03 cm
-1
throughout the region and to provide good calibrating points at frequent intervals. Some 600 rotation-vibration lines are illustrated in 20 spectrograms and wavenumbers are listed in companion tables with considerable intercomparison with worthy data obtained in other laboratories. The absorpotion bands were remeasured or calibrated by using either a precisely graduated grating circle or standard atomic lines with the fringe system formed by a
Fabry
-Perot interferometer. Characteristic features of the individual bands are discussed briefly and references to other publications are given. The substances used for calibration include H
2
O, CO
2
, CO, HCl,
HBr
, NH
3
, C
2
H
2
, CH
4
, N
2
O, and polystyrene film.
...
PMID:Vibration-Rotation Structure in Absorption Bands for the Calibration of Spectrometers From 2 to 16 Microns. 3219 55