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Query: KEGG:D01931 (TiO2)
 11,320 document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)

A novel ligand, 5,5'-(2,2'-bipyridine-4,4'-diyl)-bis(thiophene-2-carboxylic acid) (BTC), and its Ru(II) complex (BTC-1) in which the anchoring group is attached to the thiophene units were developed. Using a low-volatility electrolyte and 3.3 mum mesoporous TiO2 films BTC-1 achieved a solar-to-electricity conversion efficiency of 6.1%, compared to 4.8% for N719 under the same experimental conditions.
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PMID:Design and synthesis of a novel anchoring ligand for highly efficient thin film dye-sensitized solar cells. 1992 Oct 11

Supported metal oxide nanoparticles are important in heterogeneous catalysis; however, the ability to tailor their size, structure, and dispersion remains a challenge. A strategy to achieve well-dispersed and size-controlled supported metal oxides through the manageable growth of a metal organic framework (Cu-BTC) on TiO2 followed by pyrolysis is described.
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PMID:Well-Dispersed and Size-Controlled Supported Metal Oxide Nanoparticles Derived from MOF Composites and Further Application in Catalysis. 2580 51

Chemically functional microporous metal-organic framework (MOF) crystals are attractive for filtration and gas storage applications, and recent results show that they can be immobilized on high surface area substrates, such as fiber mats. However, fundamental knowledge is still lacking regarding initial key reaction steps in thin film MOF nucleation and growth. We find that thin inorganic nucleation layers formed by atomic layer deposition (ALD) can promote solvothermal growth of copper benzenetricarboxylate MOF (Cu-BTC) on various substrate surfaces. The nature of the ALD material affects the MOF nucleation time, crystal size and morphology, and the resulting MOF surface area per unit mass. To understand MOF nucleation mechanisms, we investigate detailed Cu-BTC MOF nucleation behavior on metal oxide powders and Al2O3, ZnO, and TiO2 layers formed by ALD on polypropylene substrates. Studying both combined and sequential MOF reactant exposure conditions, we find that during solvothermal synthesis ALD metal oxides can react with the MOF metal precursor to form double hydroxy salts that can further convert to Cu-BTC MOF. The acidic organic linker can also etch or react with the surface to form MOF from an oxide metal source, which can also function as a nucleation agent for Cu-BTC in the mixed solvothermal solution. We discuss the implications of these results for better controlled thin film MOF nucleation and growth.
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PMID:Copper Benzenetricarboxylate Metal-Organic Framework Nucleation Mechanisms on Metal Oxide Powders and Thin Films formed by Atomic Layer Deposition. 2699 31