Gene/Protein
Disease
Symptom
Drug
Enzyme
Compound
Pivot Concepts:
Gene/Protein
Disease
Symptom
Drug
Enzyme
Compound
Target Concepts:
Gene/Protein
Disease
Symptom
Drug
Enzyme
Compound
Query: EC:3.4.16.2 (
PCP
)
3,761
document(s) hit in 31,850,051 MEDLINE articles (0.00 seconds)
A racemic mixture of three-layered [3.3]paracyclophane ([3.3]
PCP
), 1, has been resolved into two enantiomers, and their absolute configuration was determined from a comparison of experimental chiroptical properties and density functional theory (DFT) calculations. A simple model comprising two p-xylenes and
1,2,4,5-tetramethylbenzene
(durene) was used to explain the origin of the chiroptical properties of the three-layered cyclophane system.
...
PMID:Optical resolution, absolute configuration, and chiroptical properties of three-layered [3.3]paracyclophane. 1893 16
